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Treatment of PDMS surfaces using pulsed DBD plasmas: comparing the use of different gases and its influence on adhesion

机译:使用脉冲DBD等离子体处理pDms表面:比较使用   不同气体及其对粘附性的影响

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摘要

In this work we present some results of the treatment of polydimethylsiloxane(PDMS) surfaces using pulsed dielectric barrier discharge plasmas. The resultsof plasma treatment using different gases and mixtures, argon, argon plus watervapor, helium, helium plus water vapor, nitrogen and nitrogen plus water vapor,were compared testing the adhesion between two PDMS samples for each kind ofplasma. We also studied the water contact angle in function of plasma processtime of PDMS surfaces with each kind of plasma treatment. The plasma wascharacterized by optical emission spectroscopy (OES) to identify the emittingspecies and determine the plasma temperatures. The plasma temperature for eachprocess was estimated comparing the spectrum obtained by OES with the spectrumgenerated by SpecAir simulation code. Measurements of power delivered to theplasmas were also performed. As the results, all the process using differentgases show good adhesion efficacy between PDMS samples when long exposure time(larger than 150 seconds) is applied. However, when only a few discharges areapplied to PDMS samples the helium plasma process presented best results.Atomic Force Microscopy (AFM) analysis of PDMS samples treated with heliumplasma showed reduction in the surface roughness, which increase the surfacecontact area and improves the adhesion.
机译:在这项工作中,我们介绍了使用脉冲介电势垒放电等离子体处理聚二甲基硅氧烷(PDMS)表面的一些结果。比较了使用不同气体和混合物,氩气,氩气加水蒸气,氦气,氦气加水蒸气,氮气和氮气加水蒸气进行等离子体处理的结果,比较了两种PDMS样品对每种等离子体的附着力。我们还研究了水接触角与各种等离子体处理对PDMS表面等离子体处理时间的影响。通过光发射光谱法(OES)对等离子体进行表征,以识别发射物种并确定等离子体温度。通过将OES获得的光谱与SpecAir模拟代码生成的光谱进行比较,估算出每个过程的等离子体温度。还测量了传递到血浆的功率。结果,当施加较长的暴露时间(大于150秒)时,所有使用不同气体的过程在PDMS样品之间都显示出良好的粘附效果。但是,当仅对PDMS样品施加少量放电时,氦等离子体工艺表现出最佳结果。原子力显微镜(AFM)分析用氦等离子体处理的PDMS样品显示出表面粗糙度降低,这增加了表面接触面积并改善了附着力。

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